You want your swimming pool or hot tub water to stay crystal-clear and clean. And chlorine is the essential additive used by most pool and tub owners to keep it that way. Yet chlorine can be tricky to work with, so understanding the differences between free chlorine and total chlorine is crucial to keep your water clean and you and your family safe.
How Chlorine Helps Your Pool Water
If you have ever seen a dark-green pond or lake, you have seen the natural work of algae. Countless billions of algae, both the green, brown, or red microalgae or the blooms of blue-green algae called cyanobacteria, grow rapidly, just like the living organisms they are.
Chlorine is the additive to water that kills algae and other harmful organisms. Municipal water is treated with chlorine but not at the level required for pool water or with the same regularity.
Chlorine in pool and spa water takes care of a host of problems. It kills pathogens such as algae and mold spores, as well as some parasites and bacteria. It can also take care of swimmers' byproducts such as blood, urine, sweat, plus oxidizing and neutralizing soaps, oils, and deodorants.
What Is Free Chlorine?
Free chlorine is the amount of chlorine present in chlorinated water that is available—or free, that is—to combine with that chlorinated water. Once the free chlorine does combine, it will begin to kill and neutralize the water's contaminants. Free chlorine is also known as chlorine residual, free chlorine residual, and residual chlorine.
What Is Combined Chlorine?
Combined chlorine is the amount of chlorine that has begun to bind to and work on the water's contaminants. The presence of combined chlorine in your pool or spa water is a good sign: It means that contaminants are being broken down.
Excessive combined chlorine works against you. If the amount of combined chlorine reaches 0.5 ppm (parts per million) or above, levels are too high and often result in that characteristic chlorine smell. If this happens, you will need to shock the water.
What Is Total Chlorine?
Total chlorine is the sum of the addition of free chlorine and combined chlorine. Use the formula F + C = T to help you with basic free chlorine vs. total chlorine concepts.
How Free, Combined, and Total Chlorine Work
When you test your pool or spa water, the free chlorine level must exceed the combined chlorine level. Think of free chlorine as the arsenal you need in order to keep the contaminants at bay. This arsenal needs to always be well-stocked and must exceed the force of the contaminants that it is combatting.
You can look at the interplay of free, combined, and total chlorine in a number of ways. For one, if the total chlorine level and free chlorine level are equal (T - F = 0), no combined chlorine is present in the water. This means that none of the combined chlorine has been used.
Another way to figure the combined chlorine level is to subtract the total chlorine level from free chlorine level, provided the total chlorine is higher than the free chlorine. Apply the formula F - T = C.
Acceptable Chlorine Levels For Safety
Test kits usually test several factors within the same kit: pH, chlorine, acid demand, and total alkalinity. More inclusive six-in-one kits test chlorine, bromine, pH, total alkalinity, total hardness, and cyanuric acid.
Test at least two to three times a week for chlorine levels (as well as for pH levels). After dipping the combined vials at least 18 inches below the surface, drop the indicator solution (or tablets) into the chlorine level section of the vials.
Most testing kits color-code the results, as well as show the reading. For most pools, the chlorine level should remain between 1 to 3 ppm. Chlorine levels lower than 1 ppm place swimmers at grave risk of contamination; never let the chlorine dip below this level. Greater chlorine levels than 3 ppm will continue to kill contaminants but will be an eye and skin irritant.